Daniel E. Falvey
Daniel E. Falvey
Professor and Associate Chair, Department of Chemistry and Biochemistry, University of Maryland
Verified email at umd.edu
Title
Cited by
Cited by
Year
Dynamics of. alpha.-CH deprotonation and. alpha.-desilylation reactions of tertiary amine cation radicals
X Zhang, SR Yeh, S Hong, M Freccero, A Albini, DE Falvey, PS Mariano
Journal of the American Chemical Society 116 (10), 4211-4220, 1994
1821994
Ab initio characterization of phenylnitrenium and phenylcarbene: remarkably different properties for isoelectronic species
CJ Cramer, FJ Dulles, DE Falvey
Journal of the American Chemical Society 116 (21), 9787-9788, 1994
1551994
Dynamics of anilinium radical α-heterolytic fragmentation processes. Electrofugal group, substituent, and medium effects on desilylation, decarboxylation, and retro-aldol …
Z Su, PS Mariano, DE Falvey, UC Yoon, SW Oh
Journal of the American Chemical Society 120 (41), 10676-10686, 1998
1291998
Model studies of DNA photorepair: Reduction potentials of thymine and cytosine cyclobutane dimers measured by fluorescence quenching
MP Scannell, DJ Fenick, SR Yeh, DE Falvey
Journal of the American Chemical Society 119 (8), 1971-1977, 1997
951997
Protecting groups that can be removed through photochemical electron transfer: Mechanistic and product studies on photosensitized release of carboxylates from phenacyl esters
A Banerjee, DE Falvey
The Journal of Organic Chemistry 62 (18), 6245-6251, 1997
941997
In vitro studies on the photobiological properties of aloe emodin and aloin A
WG Wamer, P Vath, DE Falvey
Free Radical Biology and Medicine 34 (2), 233-242, 2003
892003
Direct photolysis of phenacyl protecting groups studied by laser flash photolysis: An excited state hydrogen atom abstraction pathway leads to formation of carboxylic acids and …
A Banerjee, DE Falvey
Journal of the American Chemical Society 120 (12), 2965-2966, 1998
831998
Picosecond time scale dynamics of perester photodecomposition: evidence for an acyloxy radical intermediate in the photolysis of tert-butyl 9-methylfluorene-9-percarboxylate
DE Falvey, GB Schuster
Journal of the American Chemical Society 108 (23), 7419-7420, 1986
801986
Photochemical oxidation of water by 2-methyl-1, 4-benzoquinone: evidence against the formation of free hydroxyl radical
A Pochon, PP Vaughan, D Gan, P Vath, NV Blough, DE Falvey
The Journal of Physical Chemistry A 106 (12), 2889-2894, 2002
792002
Structures of Reactive Nitrenium Ions:  Time-Resolved Infrared Laser Flash Photolysis and Computational Studies of Substituted N-Methyl-N-arylnitrenium Ions
S Srivastava, PH Ruane, JP Toscano, MB Sullivan, CJ Cramer, ...
Journal of the American Chemical Society 122 (34), 8271-8278, 2000
782000
Model studies of DNA photorepair: radical anion cleavage of thymine dimers probed by nanosecond laser spectroscopy
SR Yeh, DE Falvey
Journal of the American Chemical Society 113 (22), 8557-8558, 1991
781991
Photoinduced electron-transfer reactions in two room-temperature ionic liquids: 1-butyl-3-methylimidazolium hexafluorophosphate and 1-octyl-3-methylimidazolium hexafluorophosphate
RC Vieira, DE Falvey
The Journal of Physical Chemistry B 111 (18), 5023-5029, 2007
742007
Photogenerated arylnitrenium ions: absorption spectra and absolute rate constants for tert-butyl (4-halo-2-acetylphenyl) nitrenium ions measured by time-resolved laser spectroscopy
GB Anderson, DE Falvey
Journal Of The American Chemical Society 115 (21), 9870-9871, 1993
741993
Photoremovable protecting groups based on electron transfer chemistry
DE Falvey, C Sundararajan
Photochemical & Photobiological Sciences 3 (9), 831-838, 2004
732004
Photogelling colloidal dispersions based on light-activated assembly of nanoparticles
K Sun, R Kumar, DE Falvey, SR Raghavan
Journal of the American Chemical Society 131 (20), 7135-7141, 2009
702009
Singlet− Triplet Splittings and 1, 2-Hydrogen Shift Barriers for Methylphenylborenide, Methylphenylcarbene, and Methylphenylnitrenium in the Gas Phase and Solution. What a …
CJ Cramer, DG Truhlar, DE Falvey
Journal of the American Chemical Society 119 (50), 12338-12342, 1997
701997
Photogenerated arylnitrenium ions: reactions of N-tert-butyl (4-substituted 2-acetylphenyl) nitrenium ions with alcohols and water studied by laser flash photolysis
RJ Robbins, LLN Yang, GB Anderson, DE Falvey
Journal of the American Chemical Society 117 (24), 6544-6552, 1995
701995
Photogenerated Diarylnitrenium Ions:  Laser Flash Photolysis and Product Studies on Diphenylnitrenium Ion Generated from Photolysis of 1-(N,N-Diphenylamino …
RJ Moran, DE Falvey
Journal of the American Chemical Society 118 (37), 8965-8966, 1996
691996
Experimental confirmation of the iminocyclohexadienyl cation-like structure of arylnitrenium ions: Time-resolved IR studies of diphenylnitrenium ion
S Srivastava, JP Toscano, RJ Moran, DE Falvey
Journal of the American Chemical Society 119 (47), 11552-11553, 1997
681997
A new photolabile protecting group for release of carboxylic acids by visible-light-induced direct and mediated electron transfer
JB Borak, DE Falvey
The Journal of organic chemistry 74 (10), 3894-3899, 2009
672009
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