Daniel E. Falvey
Daniel E. Falvey
Professor and Associate Chair, Department of Chemistry and Biochemistry, University of Maryland
Verified email at umd.edu
TitleCited byYear
Dynamics of. alpha.-CH deprotonation and. alpha.-desilylation reactions of tertiary amine cation radicals
X Zhang, SR Yeh, S Hong, M Freccero, A Albini, DE Falvey, PS Mariano
Journal of the American Chemical Society 116 (10), 4211-4220, 1994
1731994
Ab initio characterization of phenylnitrenium and phenylcarbene: remarkably different properties for isoelectronic species
CJ Cramer, FJ Dulles, DE Falvey
Journal of the American Chemical Society 116 (21), 9787-9788, 1994
1501994
Dynamics of Anilinium Radical α-Heterolytic Fragmentation Processes. Electrofugal Group, Substituent, and Medium Effects on Desilylation, Decarboxylation, and Retro-Aldol …
Z Su, PS Mariano, DE Falvey, UC Yoon, SW Oh
Journal of the American Chemical Society 120 (41), 10676-10686, 1998
1241998
Model studies of DNA photorepair: Reduction potentials of thymine and cytosine cyclobutane dimers measured by fluorescence quenching
MP Scannell, DJ Fenick, SR Yeh, DE Falvey
Journal of the American Chemical Society 119 (8), 1971-1977, 1997
951997
Protecting groups that can be removed through photochemical electron transfer: Mechanistic and product studies on photosensitized release of carboxylates from phenacyl esters
A Banerjee, DE Falvey
The Journal of Organic Chemistry 62 (18), 6245-6251, 1997
931997
In vitro studies on the photobiological properties of aloe emodin and aloin A
WG Wamer, P Vath, DE Falvey
Free Radical Biology and Medicine 34 (2), 233-242, 2003
842003
Picosecond time scale dynamics of perester photodecomposition: evidence for an acyloxy radical intermediate in the photolysis of tert-butyl 9-methylfluorene-9-percarboxylate
DE Falvey, GB Schuster
Journal of the American Chemical Society 108 (23), 7419-7420, 1986
811986
Direct photolysis of phenacyl protecting groups studied by laser flash photolysis: An excited state hydrogen atom abstraction pathway leads to formation of carboxylic acids and …
A Banerjee, DE Falvey
Journal of the American Chemical Society 120 (12), 2965-2966, 1998
801998
Model studies of DNA photorepair: radical anion cleavage of thymine dimers probed by nanosecond laser spectroscopy
SR Yeh, DE Falvey
Journal of the American Chemical Society 113 (22), 8557-8558, 1991
791991
Photochemical oxidation of water by 2-methyl-1, 4-benzoquinone: Evidence against the formation of free hydroxyl radical
A Pochon, PP Vaughan, D Gan, P Vath, NV Blough, DE Falvey
The Journal of Physical Chemistry A 106 (12), 2889-2894, 2002
772002
Structures of Reactive Nitrenium Ions:  Time-Resolved Infrared Laser Flash Photolysis and Computational Studies of Substituted N-Methyl-N-arylnitrenium Ions
S Srivastava, PH Ruane, JP Toscano, MB Sullivan, CJ Cramer, ...
Journal of the American Chemical Society 122 (34), 8271-8278, 2000
762000
Photoinduced electron-transfer reactions in two room-temperature ionic liquids: 1-butyl-3-methylimidazolium hexafluorophosphate and 1-octyl-3-methylimidazolium hexafluorophosphate
RC Vieira, DE Falvey
The Journal of Physical Chemistry B 111 (18), 5023-5029, 2007
732007
Photogenerated arylnitrenium ions: absorption spectra and absolute rate constants for tert-butyl (4-halo-2-acetylphenyl) nitrenium ions measured by time-resolved laser spectroscopy
GB Anderson, DE Falvey
Journal Of The American Chemical Society 115 (21), 9870-9871, 1993
731993
Photogenerated arylnitrenium ions: reactions of N-tert-butyl (4-substituted 2-acetylphenyl) nitrenium ions with alcohols and water studied by laser flash photolysis
RJ Robbins, LLN Yang, GB Anderson, DE Falvey
Journal of the American Chemical Society 117 (24), 6544-6552, 1995
711995
Photogelling colloidal dispersions based on light-activated assembly of nanoparticles
K Sun, R Kumar, DE Falvey, SR Raghavan
Journal of the American Chemical Society 131 (20), 7135-7141, 2009
702009
Photoremovable protecting groups based on electron transfer chemistry
DE Falvey, C Sundararajan
Photochemical & Photobiological Sciences 3 (9), 831-838, 2004
702004
Photogenerated Diarylnitrenium Ions:  Laser Flash Photolysis and Product Studies on Diphenylnitrenium Ion Generated from Photolysis of 1-(N,N-Diphenylamino …
RJ Moran, DE Falvey
Journal of the American Chemical Society 118 (37), 8965-8966, 1996
691996
Singlet− Triplet Splittings and 1, 2-Hydrogen Shift Barriers for Methylphenylborenide, Methylphenylcarbene, and Methylphenylnitrenium in the Gas Phase and Solution. What a …
CJ Cramer, DG Truhlar, DE Falvey
Journal of the American Chemical Society 119 (50), 12338-12342, 1997
681997
Experimental confirmation of the iminocyclohexadienyl cation-like structure of arylnitrenium ions: Time-resolved IR studies of diphenylnitrenium ion
S Srivastava, JP Toscano, RJ Moran, DE Falvey
Journal of the American Chemical Society 119 (47), 11552-11553, 1997
681997
Model studies of the (6-4) photoproduct DNA photolyase: Synthesis and photosensitized splitting of a thymine-5, 6-oxetane
G Prakash, DE Falvey
Journal Of The American Chemical Society 117 (45), 11375-11376, 1995
671995
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